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Creators/Authors contains: "Li, Jiajia"

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  1. Free, publicly-accessible full text available September 1, 2026
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  4. Here, we report the modelling of photo-mediated RAFT step-growth polymerization kinetics of maleimide and acrylate monomers with bifunctional RAFT agents bearing tertiary carboxyalkyl stabilized fragementable R groups. 
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    Free, publicly-accessible full text available January 1, 2026
  5. Abstract Photomediated reversible addition fragmentation chain transfer (RAFT) step‐growth polymerization is performed using a trithiocarbonate‐based chain transfer agent (CTA) and acrylate‐based monomers both with and without a photocatalyst. The versatility of photo‐mediated RAFT step‐growth is demonstrated by one‐pot synthesis of a graft copolymer via sequential monomer addition. Furthermore, oxygen‐tolerant photo‐mediated RAFT step‐growth is demonstrated, facilitated by the appropriate selection of photocatalyst and solvent pair (zinc tetraphenyl porphyrin [ZnTPP] and dimethyl sulfoxide [DMSO]), enabling ultralow volume polymerization under open‐air conditions. 
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    Free, publicly-accessible full text available January 1, 2026
  6. Here we report one-pot stimuli-responsive tandem degradation of a graft copolymer with alternating backbone functionalities. 
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  7. RAFT step-growth polymerizationviathe Z-group approach was developed, offering a facile method to prepare deconstructable (multiblock) polymers by combining RAFT chain-growth polymerization and RAFT interchange. 
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